Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.
Identifieur interne : 000964 ( Main/Exploration ); précédent : 000963; suivant : 000965Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.
Auteurs : RBID : pubmed:23468679Abstract
The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide and three facial Cl atoms. In the crystal, the lattice water mol-ecule is linked to the complex mol-ecules via O-H⋯Cl hydrogen bonds. Further weak C-H⋯Cl and C-H⋯O hydrogen bonds result in the formation of a three-dimensional structure.
DOI: 10.1107/S1600536812044698
PubMed: 23468679
Links toward previous steps (curation, corpus...)
Le document en format XML
<record><TEI><teiHeader><fileDesc><titleStmt><title xml:lang="en">Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.</title><author><name sortKey="Shirvan, Sadif A" uniqKey="Shirvan S">Sadif A Shirvan</name><affiliation wicri:level="1"><nlm:affiliation>Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.</nlm:affiliation><country xml:lang="fr">Iran</country><wicri:regionArea>Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh</wicri:regionArea></affiliation></author><author><name sortKey="Haydari Dezfuli, Sara" uniqKey="Haydari Dezfuli S">Sara Haydari Dezfuli</name></author><author><name sortKey="Khazali, Fereydoon" uniqKey="Khazali F">Fereydoon Khazali</name></author><author><name sortKey="Aghajeri, Manouchehr" uniqKey="Aghajeri M">Manouchehr Aghajeri</name></author><author><name sortKey="Borsalani, Ali" uniqKey="Borsalani A">Ali Borsalani</name></author></titleStmt><publicationStmt><date when="2012">2012</date><idno type="doi">10.1107/S1600536812044698</idno><idno type="RBID">pubmed:23468679</idno><idno type="pmid">23468679</idno><idno type="wicri:Area/Main/Corpus">000756</idno><idno type="wicri:Area/Main/Curation">000756</idno><idno type="wicri:Area/Main/Exploration">000964</idno></publicationStmt></fileDesc><profileDesc><textClass></textClass></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide and three facial Cl atoms. In the crystal, the lattice water mol-ecule is linked to the complex mol-ecules via O-H⋯Cl hydrogen bonds. Further weak C-H⋯Cl and C-H⋯O hydrogen bonds result in the formation of a three-dimensional structure.</div></front></TEI><pubmed><MedlineCitation Owner="NLM" Status="PubMed-not-MEDLINE"><PMID Version="1">23468679</PMID><DateCreated><Year>2013</Year><Month>03</Month><Day>07</Day></DateCreated><DateCompleted><Year>2013</Year><Month>03</Month><Day>08</Day></DateCompleted><DateRevised><Year>2013</Year><Month>04</Month><Day>18</Day></DateRevised><Article PubModel="Print-Electronic"><Journal><ISSN IssnType="Electronic">1600-5368</ISSN><JournalIssue CitedMedium="Print"><Volume>68</Volume><Issue>Pt 12</Issue><PubDate><Year>2012</Year><Month>Dec</Month><Day>1</Day></PubDate></JournalIssue><Title>Acta crystallographica. Section E, Structure reports online</Title><ISOAbbreviation>Acta Crystallogr Sect E Struct Rep Online</ISOAbbreviation></Journal><ArticleTitle>Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.</ArticleTitle><Pagination><MedlinePgn>m1448-9</MedlinePgn></Pagination><ELocationID EIdType="doi" ValidYN="Y">10.1107/S1600536812044698</ELocationID><Abstract><AbstractText>The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide and three facial Cl atoms. In the crystal, the lattice water mol-ecule is linked to the complex mol-ecules via O-H⋯Cl hydrogen bonds. Further weak C-H⋯Cl and C-H⋯O hydrogen bonds result in the formation of a three-dimensional structure.</AbstractText></Abstract><AuthorList CompleteYN="Y"><Author ValidYN="Y"><LastName>Shirvan</LastName><ForeName>Sadif A</ForeName><Initials>SA</Initials><Affiliation>Department of Chemistry, Omidieh Branch, Islamic Azad University, Omidieh, Iran.</Affiliation></Author><Author ValidYN="Y"><LastName>Haydari Dezfuli</LastName><ForeName>Sara</ForeName><Initials>S</Initials></Author><Author ValidYN="Y"><LastName>Khazali</LastName><ForeName>Fereydoon</ForeName><Initials>F</Initials></Author><Author ValidYN="Y"><LastName>Aghajeri</LastName><ForeName>Manouchehr</ForeName><Initials>M</Initials></Author><Author ValidYN="Y"><LastName>Borsalani</LastName><ForeName>Ali</ForeName><Initials>A</Initials></Author></AuthorList><Language>eng</Language><PublicationTypeList><PublicationType>Journal Article</PublicationType></PublicationTypeList><ArticleDate DateType="Electronic"><Year>2012</Year><Month>11</Month><Day>03</Day></ArticleDate></Article><MedlineJournalInfo><Country>United States</Country><MedlineTA>Acta Crystallogr Sect E Struct Rep Online</MedlineTA><NlmUniqueID>101089178</NlmUniqueID><ISSNLinking>1600-5368</ISSNLinking></MedlineJournalInfo><CommentsCorrectionsList><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22</RefSource><PMID Version="1">18156677</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr Sect E Struct Rep Online. 2008;64(Pt 9):m1211-2</RefSource><PMID Version="1">21201646</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr Sect E Struct Rep Online. 2012 Jun 1;68(Pt 6):m846</RefSource><PMID Version="1">22719383</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr Sect E Struct Rep Online. 2008;64(Pt 11):m1353-4</RefSource><PMID Version="1">21580816</PMID></CommentsCorrections><CommentsCorrections RefType="Cites"><RefSource>Acta Crystallogr Sect E Struct Rep Online. 2008;64(Pt 10):m1305</RefSource><PMID Version="1">21201044</PMID></CommentsCorrections></CommentsCorrectionsList><OtherID Source="NLM">PMC3588714</OtherID></MedlineCitation><PubmedData><History><PubMedPubDate PubStatus="received"><Year>2012</Year><Month>10</Month><Day>26</Day></PubMedPubDate><PubMedPubDate PubStatus="accepted"><Year>2012</Year><Month>10</Month><Day>29</Day></PubMedPubDate><PubMedPubDate PubStatus="epublish"><Year>2012</Year><Month>11</Month><Day>03</Day></PubMedPubDate><PubMedPubDate PubStatus="entrez"><Year>2013</Year><Month>3</Month><Day>8</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="pubmed"><Year>2013</Year><Month>3</Month><Day>8</Day><Hour>6</Hour><Minute>0</Minute></PubMedPubDate><PubMedPubDate PubStatus="medline"><Year>2013</Year><Month>3</Month><Day>8</Day><Hour>6</Hour><Minute>1</Minute></PubMedPubDate></History><PublicationStatus>ppublish</PublicationStatus><ArticleIdList><ArticleId IdType="doi">10.1107/S1600536812044698</ArticleId><ArticleId IdType="pii">xu5639</ArticleId><ArticleId IdType="pubmed">23468679</ArticleId><ArticleId IdType="pmc">PMC3588714</ArticleId></ArticleIdList></PubmedData></pubmed></record>Pour manipuler ce document sous Unix (Dilib)
EXPLOR_STEP=IndiumV2/Data/Main/Exploration
HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 000964 | SxmlIndent | more
Ou
HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 000964 | SxmlIndent | more
Pour mettre un lien sur cette page dans le réseau Wicri
{{Explor lien
|wiki= *** parameter Area/wikiCode missing ***
|area= IndiumV2
|flux= Main
|étape= Exploration
|type= RBID
|clé= pubmed:23468679
|texte= Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κ(2) N,N')(dimethyl-formamide-κO)indium(III) hemihydrate.
}}
Pour générer des pages wiki
HfdIndexSelect -h $EXPLOR_AREA/Data/Main/Exploration/RBID.i -Sk "pubmed:23468679" \
| HfdSelect -Kh $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd \
| NlmPubMed2Wicri -a IndiumV2
| This area was generated with Dilib version V0.5.76. |  |